期刊
ACS COMBINATORIAL SCIENCE
卷 16, 期 4, 页码 164-167出版社
AMER CHEMICAL SOC
DOI: 10.1021/co500018k
关键词
solid-phase synthesis; Glaser-Hay coupling; chemoselectivity; polyynes
资金
- Jeffress Memorial Trust
- College of William Mary
While the Glaser-Hay coupling of terminal alkynes is a useful reaction, several issues associated with chemoselectivity preclude its widespread application in synthetic chemistry. To address these issues, a solid-supported Glaser Hay methodology was developed to afford only asymmetric diyne products. This methodology was then applied to a series of immobilized alkynes with a diverse set of soluble allcynes to generate an array of heterocoupled products in high yields and purities.
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