期刊
ACS COMBINATORIAL SCIENCE
卷 15, 期 11, 页码 557-563出版社
AMER CHEMICAL SOC
DOI: 10.1021/co400107j
关键词
one-pot synthesis; three-component reaction; functionalized 2-amino-4H-pyrans; meglumine
资金
- National Natural Science Foundation of China [20872025, 21272053]
- Nature Science Foundation of Hebei Province [B2011205031]
- Training Programs of Innovation and Entrepreneurship for Undergraduates of Hebei Province [201310094021]
An efficient one-pot synthesis of functionalized 2-amino-4H-pyrans by a meglumine-catalyzed three-component reaction has been developed. A broad range of substrates including aromatic and heteroaromatic aldehydes, isatin derivatives, and acenaphthenequinone are condensed with enolizable C-H activated compounds and alkylmalonates to give the desired products in high to excellent yields. This methodology provides an alternative approach for rapid access to construct a diversity-oriented library of 4H-pyrans.
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