期刊
ACS COMBINATORIAL SCIENCE
卷 13, 期 4, 页码 436-441出版社
AMER CHEMICAL SOC
DOI: 10.1021/co200071v
关键词
dihydropyridine; 2-pyridinone; electron-deficient alkyne; beta-enamino ester; domino reaction
资金
- National Natural Science Foundation of China [20972132]
An efficient and practical synthetic method for the functionalized 2-amino hydropyridines and 2-pyridinones was successfully developed via the domino reactions of arylamines, methyl propiolate, aromatic aldehydes and the substituted acetonitriles with triethylamine as base catalyst. Reactions involving malononitrile and cyanoacetamide gave exclusively the 2-aminohydropyridines. On the other hand ethyl cyanoacetate resulted in the 2-pyridinones as main products.
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