期刊
ACS CATALYSIS
卷 8, 期 9, 页码 7734-7741出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.8b02208
关键词
manganese; pincer; pyrazine; quinoxaline; dehydrogenative coupling
资金
- European Research Council [ERC AdG 692775]
- Planning and Budgeting Committee (PBC)
Base-metal catalyzed dehydrogenative self-coupling of 2-amino alcohols to selectively form functionalized 2,5-substituted pyrazine derivatives is presented. Also, 2-substituted quinoxaline derivatives are synthesized by dehydrogenative coupling of 1,2-diaminobenzene and 1,2-diols. In both cases, water and hydrogen gas are formed as the sole byproducts. The reactions are catalyzed by acridine-based pincer complexes of earth-abundant manganese.
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