期刊
ACS CATALYSIS
卷 8, 期 9, 页码 7760-7765出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.8b02448
关键词
intermolecular cyclization; alkenes; alkynes; cyclopentene derivatives; AgSbF6 catalysis
资金
- National Natural Science Foundation of China [21672120]
- National Key Research and Development Program of China [2016YFB0401400]
- Fok Ying Tong Education Foundation of China [151014]
- Postdoctoral Foundation of the Peking-Tsinghua Joint Center for Life Sciences
We report a cationic intermolecular cyclization between simple alkenes and alkynes catalyzed by AgSbF6 with great selectivity, involving alkyl C-H bond cleavage. This methodology could supply important multisubstituted cyclopentene scaffolds. The remarkable tolerance of functional groups in the reaction allows great possibility for further transformations.
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