期刊
ACS CATALYSIS
卷 4, 期 9, 页码 3132-3135出版社
AMER CHEMICAL SOC
DOI: 10.1021/cs500859n
关键词
N-doped hydrothermal carbon; benzoic acid; chemoselective hydrogenation; heterogeneous catalyst; mild condition
资金
- National Natural Science Foundation of China [U1162124, 21376208]
- Zhejiang Provincial Natural Science Foundation for Distinguished Young Scholars of China [LR13B030001]
- Specialized Research Fund for the Doctoral Program of Higher Education [J20130060]
- Fundamental Research Funds for the Central Universities
- Program for Zhejiang Leading Team of ST Innovation
- Partner Group Program of the Zhejiang University
- Max Planck Society
A novel N-doped carbon (CN) was prepared by the hydrothermal method using glucosamine hydrochloride as both carbon and nitrogen precursor, followed by a postsynthesis heat treatment. Pd@CN exhibited 9 times higher activity compared to that of commercial Pd@AC on hydrogenation of benzoic acid to cyclohexanecarboxylic acid. The influence of solvent and substituent were also investigated. Besides, the hydrogenations of various benzoic acids have been carried out over Pd@CN.
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