期刊
ACS CATALYSIS
卷 4, 期 6, 页码 1893-1896出版社
AMER CHEMICAL SOC
DOI: 10.1021/cs500301d
关键词
Cerium oxide; carbonate; CO2; hydration; carboxylation
资金
- Cabinet Office, Government of Japan through its Funding Program for Next Generation World-leading Researchers
- Grants-in-Aid for Scientific Research [25249114] Funding Source: KAKEN
We first achieved direct synthesis of propylene carbonate from CO2 and 1,2-propanediol in excellent yield (>99%) using a carboxylation/hydration cascade catalyst of CeO2 with 2-cyanopyridine. The catalyst system can be applied to syntheses of various cyclic carbonates, including 6-membered ring carbonates that are difficult to synthesize in high yields (62->99%).
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据