期刊
ACS CATALYSIS
卷 4, 期 5, 页码 1554-1557出版社
AMER CHEMICAL SOC
DOI: 10.1021/cs500330p
关键词
Atomic Layer Deposition; Electron Microscopy; Catalyst Stability; Copper; Bifunctional Catalysis
资金
- Institute for Atom-efficient Chemical Transformations (IACT), an Energy Frontier Research Center
- U.S. Department of Energy (DOE), Office of Basic Energy Sciences
- Center for Functional Nanomaterials, Brookhaven National Laboratory
- U.S. Department of Energy, Office of Basic Energy Sciences [DE-AC02-98CH10886]
- U.S. DOE [DE-AC02-06CH11357]
- University of Wisconsin Materials Research Science and Engineering Center [DMR-1121288]
We present a model system, based on spherical nonporous supports, to facilitate the characterization of supported metal catalysts stabilized by atomic layer deposition (ALD) against sintering and leaching under liquid-phase conditions. Calcination at high temperatures (973 K) produces pores in the ALD overcoat, and we image these pores using scanning transmission electron microscopy and electron energy loss spectroscopy (STEM/EELS). We determine the size of these pores to be similar to 1 nm using small-angle X-ray scattering (SAXS). Finally, we demonstrate the use of ALD to synthesize novel bifunctional catalysts by the addition of an acidic oxide layer to the stabilizing overcoat.
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