期刊
ACS CATALYSIS
卷 4, 期 3, 页码 717-721出版社
AMER CHEMICAL SOC
DOI: 10.1021/cs401189a
关键词
metal-organic frameworks; catalysis; oligomerization; propene; nickel
资金
- BP's XC2 program
Two Ni2+-containing metal-organic frameworks, Ni-2(dobdc) and Ni-2(dobpdc), are shown to be active for the oligomerization of propene in the gas phase. The metal-organic frameworks exhibit activity comparable to Ni2+-exchanged aluminosilicates but maintain high selectivity for linear oligomers. Thus, these frameworks should enable the high yielding synthesis of linear propene oligomers for use in detergent and diesel fuel applications.
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