期刊
ACS CATALYSIS
卷 4, 期 7, 页码 2169-2174出版社
AMER CHEMICAL SOC
DOI: 10.1021/cs5004454
关键词
selective oxidation; propylene oxidation; propylene oxide; molecular oxygen; silver nanoparticles; tungsten oxide nanorod
资金
- UGC
- CSIR
- UGC, India
- Photon Factory Advisory Committee [2010G109]
- CSIR for funding Five Year Plan Project (12 FYP) [CSC-0125]
Propylene oxide (PO) is a versatile chemical intermediate, and by volume it is among the top SO chemicals produced in the world. The catalytic conversion of propylene to PO by molecular oxygen with minimum waste production is of high significance from an academic as well as an industrial point of view. We have developed a new synthesis strategy to prepare 2-5 nm metallic silver nanoparticles (AgNPs) supported on tungsten oxide (WO3) nanorods with diameters between 30 and 40 nm, in the presence of cationic surfactant (cetyltrimethylammonium bromide: CTAB), capping agent (polyvinylpyrrolidone: PVP), and hydrazine. The synergy between the surface AgNPs and WO3 nanorods facilitates the dissociation of molecular oxygen on the metallic Ag surface to produce silver oxide, which then transfers its oxygen to the propylene to form PO selectively. The catalyst exhibits a PO production rate of 6.1 X 10(-2) mol gcat(-1) h(-1), which is almost comparable with the industrial ethylene-to-ethylene oxide production rate.
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