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Recent Advances in Catalytic Conversion of Ethanol to Chemicals

期刊

ACS CATALYSIS
卷 4, 期 4, 页码 1078-1090

出版社

AMER CHEMICAL SOC
DOI: 10.1021/cs4011343

关键词

ethanol; catalyst; ethylene; isobutene; 1-butanol; hydrogen; oxygenates; gasoline

资金

  1. U.S. Department of Energy (DOE), Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences

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With increased availability and decreased cost, ethanol is potentially a promising platform molecule for the production of a variety of value-added chemicals. In this review, we provide a detailed summary of recent advances in catalytic conversion of ethanol to a wide range of chemicals and fuels. We particularly focus on catalyst advances and fundamental understanding of reaction mechanisms involved in ethanol steam reforming (ESR) to produce hydrogen, ethanol conversion to hydrocarbons ranging from light olefins to longer chain alkenes/alkanes and aromatics, and ethanol conversion to other oxygenates including 1-butanol, acetaldehyde, acetone, diethyl ether, and ethyl acetate.

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