期刊
ACS CATALYSIS
卷 3, 期 11, 页码 2522-2526出版社
AMER CHEMICAL SOC
DOI: 10.1021/cs4006869
关键词
metal-ligand cooperation; ruthenium; CO2 hydrogenation; pincer catalyst
资金
- Technology Foundation STW
- Netherlands Organization for Scientific Research (NWO)
- NWO
The metal-ligand cooperative activation of CO2 with pyridine-based ruthenium PNP pincer catalysts leads to pronounced inhibition of the activity in the catalytic CO2 hydrogenation to formic acid. The addition of water restores catalytic performance by activating alternative reaction pathways and leads to unprecedented Ru-catalyzed CO2 hydrogenation activity. The mechanism of the underlying chemical transformations is proposed on the basis of DFT calculations, kinetic experiments, and NMR reactivity studies.
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