期刊
ACS CATALYSIS
卷 3, 期 6, 页码 1076-1091出版社
AMER CHEMICAL SOC
DOI: 10.1021/cs400138b
关键词
aminohalogenation; catalysis; enantioselelective; alkenes; alkynes; allenes; haloamines; haloamidation
资金
- National Institutes of Health [GM078383]
Catalytic aminohalogenation methods enable the regio- and stereoselective vicinal difunctionalization of alkynes, allenes, and alkenes with amine and halogen moieties. A range of protocols and reaction mechanisms including organometallic, Lewis base, Lewis acid, and Bronsted acid catalysis have been disclosed, enabling the regio- and stereoselective synthesis of halogen-functionalized acyclic amines and nitrogen heterocycles. Recent advances including aminofluorination and catalytic enantioselective aminohalogenation reactions are summarized in this review.
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