期刊
ACS CATALYSIS
卷 3, 期 4, 页码 540-553出版社
AMER CHEMICAL SOC
DOI: 10.1021/cs300801y
关键词
spirooxindole; asymmetric; catalytic; spirocyclic; spirocenter; spiroketals; spirolactones
Spirocycles provide an exciting platform to develop and understand the reactivity and selectivity for a wide variety of catalysts while affording diverse strategies to access molecules with important applications. This review features recent examples in which a spirocenter is formed within the key step of a catalytic asymmetric process, in either an intramolecular or intermolecular fashion. Examples highlight notable spirocyclization strategies and compare the reactivity and selectivity for different classes of chiral organocatalysts and organometallic catalysts.
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