期刊
ACS CATALYSIS
卷 3, 期 3, 页码 287-293出版社
AMER CHEMICAL SOC
DOI: 10.1021/cs300719r
关键词
alkoxycarbonylation reaction; aminocarbonylation reaction; immobilization; phenoxycarbonylation reaction; palladium
资金
- University Grant Commission (UGC) India
- Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan
- MEXT, Japan
- Grants-in-Aid for Scientific Research [22350005] Funding Source: KAKEN
Immobilized palladium metal-containing ionic liquid (ImmPd-IL), a structurally well-defined transition metal complex, is explored as an immobilized, phosphine-free catalyst for carbonylation reactions, including alkoxycarbonylation, phenoxycarbonylation, and aminocarbonylation reactions. The effect of various reaction parameters, such as solvent, base, time, temperature, and CO pressure on carbonylation reactions using ImmPd-IL catalyst was investigated. The optimized protocol was applied to a wide variety of substituted aryl iodides and various alcohol/phenols and amines having different steric and electronic properties and afforded the corresponding products in good to excellent yield. The developed catalytic system circumvents the use of phosphine ligands, with an additional advantage of palladium catalyst recovery and reuse for up to four consecutive cycles. The recycled catalyst was characterized using XPS analysis.
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