期刊
ACS CATALYSIS
卷 3, 期 10, 页码 2327-2335出版社
AMER CHEMICAL SOC
DOI: 10.1021/cs400534x
关键词
Pd catalysts; preparation; hydrogenation; succinic acid; gamma-butyrolactone
资金
- French Agence Nationale de la Recherche within the Programme Chimie et Procedes pour le Developpement Durable CP2D (HCHAIB)
- AXELERA
A series of 2 wt % Pd/TiO2 monometallic catalysts were prepared by varying some parameters, such as the nature of the precursor salt, the titania support, and the preparation method. The structural and textural properties of the catalytic systems were fully characterized by several physical and chemical techniques (inductively coupled plasma optical emission spectrometry, N-2 physisorption, H-2 chemisorption, transmission.electron microscopy coupled with energy dispersive X-ray spectroscopy, powder X-ray diffraction, temperature programmed reduction, X-ray photoelectron spectroscopy, and gas phase reaction of cyclohexane dehydrogenation). The catalytic performances were further estimated for the hydrogenation of an aqueous solution of succinic acid (SUC) performed in a batch reactor at 160 degrees C and under 150 bar total pressure. The results showed that all the Pd catalysts are very Selective to produce gamma-butyrolactone, the first hydrogenated product. However, the rate of succinic acid conversion is a function of both the Pd dispersion and the preparation method. The deposition-precipitation method allows one to obtain the highest performing 2 wt % Pd/TiO2 samples during SUC hydrogenation in terms of activity and stability.
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