4.8 Article

Enhancement in Aerobic Alcohol Oxidation Catalysis of Au25 Clusters by Single Pd Atom Doping

期刊

ACS CATALYSIS
卷 2, 期 7, 页码 1519-1523

出版社

AMER CHEMICAL SOC
DOI: 10.1021/cs300252g

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Au-25 clusters; single Pd atom doping; aerobic oxidation; multiwalled carbon nanotubes

资金

  1. Funding Program for Next Generation World-Leading Researchers (NEXT Program) [GR-003]
  2. Grants-in-Aid for Scientific Research [23750001] Funding Source: KAKEN

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Au-25 uzs and Pd1Au24 clusters on multiwalled carbon nanotubes were developed via adsorption of Au-25(SC12H25)(18) and Pd1Au24(SC12H25)(18), respectively, on the nanotubes, followed by calcination. Comparison of their catalysis for the aerobic oxidation of benzyl alcohol showed that single Pd atom doping significantly improved the catalytic performance of Au25 for the first time

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