4.8 Article

Photocatalytic H2O2 Production from Ethanol/O2 System Using TiO2 Loaded with Au-Ag Bimetallic Alloy Nanoparticles

期刊

ACS CATALYSIS
卷 2, 期 4, 页码 599-603

出版社

AMER CHEMICAL SOC
DOI: 10.1021/cs2006873

关键词

photocatalysis; titanium dioxide; nanoparticle; alloy; hydrogen peroxide

资金

  1. Ministry of Education, Culture, Sports, Science, and Technology, Japan (MEXT) [23360349]
  2. Grants-in-Aid for Scientific Research [23360349, 10J01210] Funding Source: KAKEN

向作者/读者索取更多资源

TiO2 loaded with Au-Ag bimetallic alloy particles efficiently produces H2O2 from an O-2-saturated ethanol/water mixture under UV irradiation. This is achieved via the double effects created by the alloy particles. One is the efficient photocatalytic reduction of O-2 on the Au atoms promoting enhanced H2O2 Formation, due to the efficient separation of photoformed electron-hole pairs at the alloy/TiO2 heterojunction. Second is the suppressed photocatalytic decomposition of formed H2O2 due to the decreased adsorption of H2O2 onto the Au atoms.

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