4.8 Article

Cooperativity in Aqueous Organometallic Catalysis: Contribution of Cyclodextrin-Substituted Polymers

期刊

ACS CATALYSIS
卷 2, 期 7, 页码 1417-1420

出版社

AMER CHEMICAL SOC
DOI: 10.1021/cs300254t

关键词

cyclodextrins; polymer; biphasic catalysis; molecular recognition; cooperative effects

资金

  1. Region Nord-Pas-Calais
  2. Centre National de la Recherche Scientifique (CNRS)

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Cooperativity has been implicated to explain the catalytic performances of cyclodextrin-substituted polymers in aqueous rhodium catalyzed hydroformylation of 1-hexadecene, thus opening the door to the transformation of very hydrophobic substrates in aqueous biphasic catalysis by supramolecular means.

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