期刊
ACS CATALYSIS
卷 2, 期 11, 页码 2247-2249出版社
AMER CHEMICAL SOC
DOI: 10.1021/cs300428f
关键词
fructose; 5-(hydroxymethyl)-2-furaldehyde; levulinic acid; formic acid; gamma-valerolactone; acid catalysis; Shvo-catalyst; sulfuric acid; isotope labeling
资金
- City University of Hong Kong [9380047]
The one-pot conversion of fructose to gamma-valerolactone (GVL) in GVL as solvent was confirmed by monitoring the dehydration of C-13(6)-D-fructose to C-13(6)-5-(hydroxymethyl)-2-furaldehyde (C-13(6)-HMF), the hydration of C-13(6)-HMF to C-13(5)-levulinic and C-13-formic acids, followed by their conversion to C-13(5)-GVL.
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