期刊
ACS CATALYSIS
卷 2, 期 1, 页码 95-119出版社
AMER CHEMICAL SOC
DOI: 10.1021/cs200562n
关键词
rhodium-catalyzed asymmetric arylation; conjugate addition; phosphorus ligands; diene ligands; bissulfoxide ligands; hybrid ligands; activated alkenes; imines; tandem reactions
资金
- National Natural Science Foundation of China [21102161]
- State Key Laboratory of Bio-organic and Natural Products Chemistry (Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences)
Rhodium-catalyzed asymmetric arylation (RCAA) reactions provide one of the most straightforward and powerful ways to introduce aryl fragments in an enantioselective manner. The discovery of novel chiral ligands and catalytic systems is a major focus in generating optical chiralities for RCAA reactions. In the past decade, the chelating functionalities in ligands have been significantly expanded from traditional phosphorus to interesting diene, bissulfoxide, and their hybrids. Herein we highlight the research on these distinct families of chiral ligands and describe their applications in the RCAA of arylmetals to activated alkenes, aldehydes, ketones and imines, and RCAA-tandem reactions.
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