期刊
ACS CATALYSIS
卷 1, 期 10, 页码 1178-1182出版社
AMER CHEMICAL SOC
DOI: 10.1021/cs200224b
关键词
Zinc; catalysis; transesterification; cluster; additive effects; DMAP
资金
- CREST from JST
- MEXT
- Hoh-ansha Foundation
- Kurata Grants
- Osaka University
- JSPS
- Grants-in-Aid for Scientific Research [22750094, 21245027, 22105010, 22106525, 10J01533, 21390003] Funding Source: KAKEN
A catalytic amount of 4-dimethylaminopyridine showed drastic additive effects on transesterification catalyzed by the mu(4)-oxo-tetranuclear zinc cluster Zn-4(OCOCF3)(6)O, enhancing the catalytic activity by more than 15-fold. The new catalyst system facilitates transesterification of less reactive sterically demanding esters and alcohols.
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