期刊
ACS CATALYSIS
卷 2, 期 1, 页码 163-167出版社
AMER CHEMICAL SOC
DOI: 10.1021/cs2003577
关键词
C-H activation; oxidation; amination; rhenium complexes; transition metal catalysis
资金
- National Natural Science Foundation of China [20832001, 20972065, 21074054]
- National Basic Research Program of China [2007CB925103, 2010CB923303]
An efficient method for the oxidation of benzylic sp(3) C-H bond to produce ketones or esters using rhenium(V) complexes as catalysts has been developed. Moreover, the amination of benzylic sp(3) C-H bond with NH2Ts in the presence of NBS has also been reported in moderate to good yields under the catalyst of rhenium(V)-based complexes.
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