期刊
NATURE COMMUNICATIONS
卷 2, 期 -, 页码 -出版社
NATURE PUBLISHING GROUP
DOI: 10.1038/ncomms1505
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资金
- KAKENHI [21685005, 20108015, 22550094]
- JST
- Global COE program (Molecular Complex Chemistry)
- Grants-in-Aid for Scientific Research [21685005, 22550094, 20108001, 20108015] Funding Source: KAKEN
The bottom-up synthesis of hoop-shaped aromatic hydrocarbons is currently attracting interest, because they can serve as finite models of single-wall carbon nanotubes (SWNTs). Models for chiral (n,m)-SWNTs, particularly those with optical activity, have not been synthesized but are of special interest owing to their anomalous helical network of sp(2)-carbons. Here we show that finite model compounds for (12,8)-, (11,9)- and (10,10)-SWNTs are synthetically accessible by a stepwise macrocyclization of [4]phenacene, a compound that bears fused benzene rings in a zigzag arrangement, and we can isolate and identify all the isomers including the enantiomers with (P)- and (M)-helicity. The complete isolation and identification of the model compounds led to the first examination of the stereo-disproportionation of chiral SWNT models, which encourages the future studies on asymmetric induction for the synthesis.
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