期刊
JOURNAL OF MATERIALS CHEMISTRY C
卷 3, 期 39, 页码 10066-10069出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5tc02256h
关键词
-
资金
- Major State Basic Research Development Program of China [2011CB932501, 2013CB834504]
- Chinese Academy of Science
Two new 2D covalent organic frameworks (COFs) with a regular honeycomb lattice, TAT-COF-1 and TAT-COF-2, were synthesized based on triazatruxene derivatives. The two COFs, especially TAT-COF-2, have a large BET surface area, good crystallinity, moderate to good hydrogen and carbon dioxide adsorption abilities and also possess good CO2/N-2 selectivity. When suspended in ethanol, the fluorescence of TAT-COF-2 could be enhanced or quenched by different solvents. It also shows a rapid fluorescence-on and fluorescence-off nature towards electron rich and deficient arene vapors, respectively. After being exposed to electron-rich arene vapors, the enhanced fluorescence intensity can be recovered to normal level after 5 minutes in an ambient atmosphere, which means the sample could be reused conveniently for detecting electron rich arene vapors.
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