期刊
JOURNAL OF MATERIALS CHEMISTRY C
卷 3, 期 15, 页码 3708-3713出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5tc00005j
关键词
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资金
- SERC [1123004036]
Poly(vinylidene fluoride) (PVDF) homopolymer and its copolymers in their beta phases are the most promising polymeric materials for electroactive devices. In this work, a simple and effective strategy is developed to fabricate beta-poly(vinylidene fluoride-co-hexafluoropropylene) (beta-PVDF-hfp) with characteristic piezo-/ferroelectric properties using mesoporous SiO2 nanorods. The nanorods offer 2-fold arrangement for the -OH groups, namely, anisotropic rod shape and ordered mesopores. We report, for the first time in the PVDF system, the direct evidence of hydrogen bond interaction during beta phase formation through XPS analysis. Our study further reveals that besides well-known facilitation by intermolecular interaction, the arrangement of surface functional groups is essential for the formation of beta-PVDF-hfp. This proposed mechanism manages to explain the current controversy in the formation mechanism. We further demonstrate that our approach can be extended to a wider intermolecular interaction regime than hydrogen bonding, thus benefitting current development in PVDF homo/copolymer-based electroactive devices.
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