期刊
JOURNAL OF MATERIALS CHEMISTRY C
卷 3, 期 43, 页码 11412-11422出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5tc02046h
关键词
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资金
- NSF [DMR-1207585]
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [1207585] Funding Source: National Science Foundation
A series of mesogenic derivatives of o-carborane was synthesized, their properties were analyzed by thermal, optical and XRD methods, and results were compared with those of isostructural p-carborane and benzene analogues. Comparative analysis revealed lower nematic phase stability and enhanced smectic behavior, including SmC, in the o-carborane derivatives relative to the isosteric p-carborane analogues. The effect of o-carborane on the electrooptical properties was assessed for biphenyl derivative 1[B]a in the 6CHBT nematic host giving the extrapolated Delta epsilon = 11.0, and a moderate increase of the elastic constants K-ii. Complete analysis of the dielectric results for o-carborane and p-carborane analogues 1[B]a and 1[A]a was performed using the Maier-Meier formalism augmented by DFT computational methods.
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