期刊
JOURNAL OF MATERIALS CHEMISTRY C
卷 3, 期 3, 页码 538-550出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4tc02037e
关键词
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资金
- NSFC [20972024, 21273028, 21421005, 21473020]
- Royal Society (UK)
- NSFC (China-UK Cost-Share Science Networks) [21011130154]
- Ministry of Education [SRFDP-20120041130005]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT_13R06]
- Fundamental Research Funds for the Central Universities [DUT14ZD226]
- Dalian University of Technology [DUT2013TB07]
In order to switch the triplet excited states in organic compounds, dimethylaminostyryl BODIPY-C-60 dyads and triads were prepared. The triplet excited states of the compounds were switched with acid/base, and the mechanism was studied with nanosecond time-resolved transient difference absorption spectroscopy. The visible light-harvesting BODIPY antennas are the electron or singlet energy donor, whereas C-60 moiety is the electron/singlet energy acceptor, as well as the spin converter to produce triplet excited states. Our strategy of triplet state switching is to control either the photoinduced electron transfer (PET) or the singlet state energy transfer (EnT) from the antenna to C-60 moiety by protonation of the dimethylaminostyryl BODIPY unit. Population of the triplet state was observed for the dyads with mono(4-dimethylaminostyryl) substituents on BODIPY antenna in nonpolar solvent such as toluene (tau(T) = 168.6 mu s). Formation of the charge transfer state (CTS) in polar solvent quenches the triplet excited state (tau(T) < 10 ns). In the presence of acid, the dimethylaminostyryl BODIPY moiety is protonated, thus the electron transfer (ET) was inhibited. The cascade acid-activated EnT and the intersystem crossing (ISC) of C-60 produce the triplet excited state. For the dyad and the triads with bis(4-dimethylaminostyryl) substituents on BODIPY antenna, the antenna S-1 state energy level is lower than the S-1 state energy level of C-60; thus, no EnT to C-60 exists, and no triplet state was produced upon selective excitation into the BODIPY moiety. With protonation of the amino styryl substituents, the S-1 state energy level of the antenna is promoted to be higher than S-1 state of C-60 moiety, and as a result EnT is activated and triplet state is produced. In all the compounds, the triplet excited state is localized on the dimethylaminostyryl BODIPY moiety and not on the C-60 moiety. The triplet state switching was conveyed to the singlet oxygen (O-1(2)) photosensitizing ability of the compounds, and the variation of the singlet oxygen quantum yield, Phi(Delta), is from 1.9% to 73%.
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