期刊
JOURNAL OF CHEMICAL RESEARCH
卷 -, 期 12, 页码 675-677出版社
SCIENCE REVIEWS 2000 LTD
DOI: 10.3184/174751911X13206824040536
关键词
Tollens reagent; aldehyde; gem diol; free radical
The Tollens test for aldehydes has been used for over 100 years but no reason has been given for adding sodium hydroxide to the silver nitrate before the solution is cleared with ammonia. In this paper, a mechanism is proposed which explains why the addition of alkali makes the test much more sensitive.
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