期刊
JOURNAL OF CHEMICAL RESEARCH
卷 -, 期 6, 页码 370-373出版社
SCIENCE REVIEWS 2000 LTD
DOI: 10.3184/030823409X460939
关键词
2-methyltetrahydrofuran; Grignard reactions; carbonyl compounds; alcohol synthesis
资金
- National Key Technology RD Program [2007BAI34B01]
- National Natural Science Foundation of China [20676123]
Compared with tetrahydrofuran (THF) as a solvent for the addition reactions between Grignard reagents and carbonyl compounds 2-methyltetrahydrofuran affords the corresponding adducts in higher yields with higher chemoselectivities. Moreover, 2-methyltetrahydrofuran can be readily recycled and reused, which lowers the cost of the process and makes the reaction greener.
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