期刊
CHEMICAL SCIENCE
卷 9, 期 44, 页码 8363-8368出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8sc03081b
关键词
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资金
- Scripps Research Institute (TSRI)
- Pfizer, Inc.
- Bristol-Myers Squibb
- National Institutes of Health [1R35GM125052]
A catalytic -selective syn-hydroarylation of alkenyl carbonyl compounds using arylboronic acids has been developed using a substrate directivity approach with a palladium(ii) catalyst. This method tolerates a wide range of functionalized (hetero)arylboronic acids and a variety of substitution patterns on the alkene. Preliminary mechanistic studies suggest that transmetalation is rate-limiting.
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