期刊
CHEMICAL SCIENCE
卷 9, 期 40, 页码 7822-7828出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8sc02875c
关键词
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资金
- Deutsche Forschungsgemeinschaft [DFG Ra 1732/7, SFB 858, Ge 514/6]
- Deutscher Akademischer Austauschdienst (DAAD)
- University of St. Andrews
- EPSRC [EP/M02105X/1]
We report cationic Ir(III) complexes functionalized with adamantyl groups designed to bind to beta-cyclodextrin vesicles (CDV) with high affinity (K-a = 1 x 10(6) M-1). The emission of the complexes is tuned by changing the nature of the cyclometalating ligands. The host-guest adduct of CDV and Ir(III) complexes shows increased and significantly blue-shifted emission due to the lower mobility of the Ir(III)-complexes residing in the less polar environment of the vesicle surface. Ir(III)-decorated CDV are efficiently taken up by cells and can be used in live cell imaging. The CDV act as carriers to transport the phosphorescent complexes into cells where they selectively stain mitochondria.
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