期刊
CHEMICAL SCIENCE
卷 5, 期 12, 页码 4895-4905出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4sc02033b
关键词
-
资金
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-98CH10886]
- Deutscher Akademischer Austaush Dienst (DAAD)
- Excellence Initiative of the German federal and state government
- U.S. Department of Energy, Office of Basic Energy Sciences [DEAC02-98CH10886]
Ruthenium nanoparticles were immobilized onto an acidic supported ionic liquid phase ( RuNPs@SILP) in the development of bifunctional catalysts for the selective deoxygenation of biomass substrates. RuNPs@SILPs possessed high catalytic activities, selectivities and recyclabilities in the hydrogenolytic deoxygenation and ring opening of C-8- and C-9-substrates derived from furfural or 5-hydroxymethylfurfural and acetone. Tailoring the acidity of the SILP through the ionic liquid loading provided a molecular parameter by which the catalytic activity and selectivity of the RuNPs@SILPs were controlled to provide a flexible catalyst system toward the formation of different classes of value-added products: cyclic ethers, primary alcohols or aliphatic ethers.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据