期刊
CHEMICAL SCIENCE
卷 5, 期 1, 页码 267-274出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3sc52487f
关键词
-
资金
- National Institutes of Health [GM065313]
The reaction of soluble iron-oxygen-potassium assemblies with N-2 gives insight into the mechanisms of multimetallic N-2 coordination. We report a series of very electron-rich three-coordinate, beta-diketiminate-supported iron(I) phenoxide complexes, which are metastable but have been characterized under Ar by both crystallography and solution methods. Both monomeric and dimeric Fe-OPh-K compounds have been characterized, and their iron environments are very similar in the solid and solution states. In the dimer, potassium ions hold together the phenoxide oxygens and aryl rings of the two halves, to give a flexible diiron core. The reactions of the monomeric and dimeric iron(I) compounds with N-2 are surprisingly different: the mononuclear iron(I) complexes give no reaction with N-2, but the dimeric Fe2K2 complex reacts rapidly to give a diiron-N-2 product. Computational studies show that the key to the rapid N-2 reaction of the dimer is the preorganization of the two iron atoms. Thus, cooperation between Fe (which weakens the N-N bond) and K (which orients the Fe atoms) can be used to create a low-energy pathway for N-2 reactions.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据