期刊
CHEMICAL SCIENCE
卷 5, 期 6, 页码 2336-2339出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4sc00602j
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资金
- National Institute of General Medical Science of the National Institutes of Health [R01GM063540, F32GM099254]
- University of Utah
Pd-catalyzed allylic relay Suzuki cross-coupling reactions of secondary alkyl tosylates, featuring a stericallyhindered oxidative addition and precise control of beta-hydride elimination, are reported. The identification of a linear free energy relationship between the relative rates of substrate consumption and the electronic nature of the substrate alkene suggests that the oxidative addition requires direct alkene involvement. A study of the effect of alkyl chain length on the reaction outcome supports a chelation-controlled oxidative addition.
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