期刊
CHEMICAL SCIENCE
卷 5, 期 5, 页码 1915-1927出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3sc53442a
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资金
- Ministere de l'Education Nationale, de la Recherche et de la Technologie
- Centre National de la Recherche Scientifique (CNRS)
- ANR [12-BS07-0004METALHEL- 01]
- LEA MMC Rennes-Durham
- National Science Foundation [CHE 0952253, CHE 1265833]
- Polish Science Homing Plus programme
- European Regional Development Fund under the Operational Programme Innovative Economy
- Ministry of Science and Higher Education in Poland `Outstanding Young Scientist' scholarship
- University at Buffalo for providing computational resources
- National Institute of Health, Minority Biomedical Research [1 SC3 GM089589-03, 3 S06 GM008192-27S1]
- Henry Dreyfus Teacher-Scholar Award
- NIH (RISE) [5R25GM071381]
- MARC [2T34GM008253-26]
- NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [S06GM008192, T34GM008253, R25GM071381, SC3GM089589] Funding Source: NIH RePORTER
Enantiopure mono-cycloplatinated-[8] helicene and bis-cycloplatinated-[6] helicene derivatives were prepared through column chromatography combined with crystallization of diastereomeric complexes using a chiral ancillary sulfoxide ligand. The UV-visible spectra, circular dichroism, molar rotations, and (circularly polarized) luminescence activity of these new helical complexes have been examined in detail and analysed with the help of first-principles quantum-chemical calculations.
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