期刊
CHEMICAL SCIENCE
卷 5, 期 3, 页码 1175-1178出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3sc53261e
关键词
-
资金
- NSF [CHE 1152996]
- Johns Hopkins
We disclose a new approach to the catalysis of alkane fluorination employing ultraviolet light and a photosensitizer, 1,2,4,5-tetracyanobenzene (TCB). The process is efficient, mild, and operationally straightforward. We demonstrate reaction utility on a variety of substrates, from simple hydrocarbons to complex natural products. In a showcase example, we establish that the Well-known photochemical rearrangement of alpha-santonin can be supplanted by a highly selective catalyzed fluorination.
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