期刊
CHEMICAL SCIENCE
卷 5, 期 2, 页码 462-470出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3sc52538d
关键词
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资金
- National Institute of General Medical Sciences, National Institutes of Health
- National Science Foundation
- NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R01GM036700] Funding Source: NIH RePORTER
Torsional effects control the pi-facial stereoselectivities of a variety of synthetically important organic reactions. This review surveys theoretical calculations that have led to the understanding of the influence of the torsional effects on several types of stereoselective organic reactions, especially electrophilic additions and cycloadditions to alkenes.
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