期刊
CHEMICAL SCIENCE
卷 5, 期 7, 页码 2889-2892出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4sc00743c
关键词
-
资金
- NSF
Perfluoroketones are useful products and intermediates in medicinal chemistry. Herein, cobalt-mediated fluoroacylation of 1,3-dienes is described using perfluorinated anhydrides such as TFAA. The reaction is thought to proceed through a fluoroacylcobalt reagent formed in situ. Perfluoroacylation of 1,3 dienes can also be performed to attain longer chain perfluorinated ketones.
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