期刊
CHEMICAL SCIENCE
卷 4, 期 6, 页码 2670-2674出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3sc50773d
关键词
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资金
- NSF [CHE7096481]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1048804] Funding Source: National Science Foundation
A highly efficient, base-free, mild protocol for the palladium-catalyzed, copper-activated desulfitative couplings of vinyl and aryl beta-nitrothioethers generates a wide variety of conjugated nitroorganics. Orthogonality to traditional Suzuki-Miyaura coupling is demonstrated, as well as synthetic utility, through reductive Cadogan cyclization, for the formation of indoles, carbazoles, and pyrroles.
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