期刊
CHEMICAL SCIENCE
卷 4, 期 9, 页码 3753-3757出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3sc51206a
关键词
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资金
- JSPS [220GR049]
- MEXT [25105720]
- Grants-in-Aid for Scientific Research [25708005, 25105720] Funding Source: KAKEN
An aerobic oxidative coupling of arenes/alkenes with arylboronic acids (C-H/C-B coupling) using catalytic Pd(II)-sulfoxide-oxazoline (sox) ligand and iron-phthalocyanine (FePc) has been developed. This dual catalyst system enables the synthesis of sterically hindered heterobiaryls and styrene derivatives under air without stoichiometric co-oxidants. Additionally, this chemistry demonstrated an advance toward an enantioselective biaryl coupling through C-H functionalization.
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