期刊
CHEMICAL SCIENCE
卷 4, 期 3, 页码 1281-1286出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2sc22131d
关键词
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资金
- National Natural Science Foundation of China [21172106, 21074054]
- National Basic Research Program of China [2010CB923303]
- Research Fund for the Doctoral Program of Higher Education of China [20120091110010]
- MOE
The bicyclic isoxazolidine scaffolds are the ubiquitously recurring motifs in alkaloids. Despite of their facile biosynthesises in nature, the laboratory synthesis of these derivatives is still complicated. In this paper, the isoxazolidine derivatives are concisely constructed in one process with excellent stereoselectivity from simple tertiary amines through a C-H activation-retro-aza-Michael-oxidation-cyclization tandem sequence by means of visible-light. This protocol provides a concise approach to dactylicapnosinine derivatives.
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