期刊
CHEMICAL SCIENCE
卷 4, 期 6, 页码 2613-2618出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3sc50666e
关键词
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资金
- Singapore National Research Foundation (NRF)
- Singapore Economic Development Board (EDB)
- GlaxoSmithKline (GSK)
- Nanyang Technological University (NTU)
The first successful generation of cis-homoenolate equivalents from cis-enals under the catalysis of N-heterocyclic carbenes (NHCs) has been realized. The cis-homoenolate intermediates undergo effective reactions with alpha,beta-unsaturated imines to afford chiral cyclic ketone products. Compared to the trans-enals, cis-enals show different stereoselectivities and new reactivity patterns.
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