期刊
CHEMICAL SCIENCE
卷 4, 期 2, 页码 858-862出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2sc21499g
关键词
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资金
- National Boron Research Institute (BOREN)
- Turkish Academy of Sciences (TUBA)
- TUBITAK
- UNAM
Guided by the digital design concepts, we synthesized a two-module molecular demultiplexer (DEMUX) where the output is switched between emission at near IR, and cytotoxic singlet oxygen, with light at 625 nm as the input (I), and acid as the control (c). In the neutral form, the compound fluoresces brightly under excitation at 625 nm, however, acid addition moves the absorption bands of the two modules in opposite directions, resulting in an effective reversal of excitation energy transfer direction, with a concomitant upsurge of singlet oxygen generation and decrease in emission intensity.
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