期刊
CHEMICAL SCIENCE
卷 3, 期 1, 页码 58-61出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1sc00556a
关键词
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资金
- NIHGMS [R01 01 GM093213-01]
- Natural Sciences and Engineering Research Council (NSERC)
A new enantioselective alpha-oxidation of aldehydes has been accomplished using TEMPO and a synergistic combination of copper and organic catalysis. Expanding upon recently reported mechanistic studies, these mild catalytic conditions provide stable aldehyde products bearing a wide array of electronically and sterically diverse substructures. The utility of these oxidized products is highlighted by subsequent derivatization to a variety of common chiral synthons, without loss in enantiopurity.
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