期刊
CHEMICAL SCIENCE
卷 3, 期 6, 页码 2165-2169出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2sc20277h
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资金
- JSPS [220GR049]
- MEXT [23105517]
A new Pd-catalyzed C-H/C-B coupling of sterically hindered heteroarenes and arylboronic acids has been identified. The newly established Pd(OAc)(2)/bisoxazoline/TEMPO system not only enables the synthesis of sterically hindered heterobiaryls but also offers an opportunity for enantioselective biaryl coupling through C-H functionalization.
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