期刊
CHEMICAL SCIENCE
卷 3, 期 6, 页码 1851-1857出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2sc20072d
关键词
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资金
- Ligue Nationale Contre le Cancer (LNCC)
- MINECO (Spain) [CTQ2009-08536]
The ready synthesis of a new double-lasso molecular machine from an ends-activated [c2]daisy chain has been achieved. This original architecture consists of a unique double-lasso structure, where the two macrocycles can slide along the threaded pseudo-macrocycle upon variation of pH. The interlocked structure allows for two very different conformations: at low pH, it has a loose conformation with a big cavity. The interlocked molecule thus behaves like a controllable jump rope. After deprotonation, the molecule adopts a helical-type tightened conformation with a shrunken cavity. In this conformation, no jump rope movement is possible due to the tightened lasso.
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