期刊
CHEMICAL SCIENCE
卷 3, 期 3, 页码 874-877出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1sc00589h
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资金
- University of Colorado
- NSF MAST Center
- NSF [DMR-1055705]
- Directorate For Engineering
- Div Of Industrial Innovation & Partnersh [1034710] Funding Source: National Science Foundation
- Directorate For Engineering
- Div Of Industrial Innovation & Partnersh [1034720] Funding Source: National Science Foundation
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [1055705] Funding Source: National Science Foundation
A series of organic cage frameworks (OCFs) were successfully synthesized through microwave-assisted Sonogashira coupling of 3-D molecular cage building blocks with various diacetylene linkers. These novel framework materials exhibited unprecedented, high ideal selectivity (up to 213/1) in adsorption of CO2 over N-2 under ambient conditions.
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