期刊
CHEMICAL SCIENCE
卷 3, 期 6, 页码 1938-1944出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2sc00950a
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资金
- Air Force Office of Scientific Research [FA-9550-07-1-0534]
- DTRA [HDTRA1-10-0023]
Box-like tetrakis(metalloporphyrin) supramolecular assemblies possessing Zn and Al metal sites can catalyze the methanolysis of phosphate triesters with a high rate enhancement, up to 430 times faster than the uncatalyzed reaction. Mechanistic studies suggest that the observed rate enhancement can be attributed to a high local concentration of methoxide ion that operates in concert with a solvophobically driven encapsulation of substrates by the porphyrinic assembly.
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