期刊
CHEMICAL SCIENCE
卷 3, 期 7, 页码 2340-2345出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2sc20343j
关键词
-
资金
- JSPS [220GR049]
The first size-selective synthesis of [9]-[11] and [13]cycloparaphenylenes (CPP) has been achieved by strategically utilizing cis-1,4-diphenylcyclohexane-1,4-diyl as the key terphenyl-convertible L-shaped unit. To access the designed triangular or rectangular macrocyclic precursors, we utilized palladium-catalysed C-B/C-Br cross-coupling (Suzuki-Miyaura coupling) and/or nickel-mediated C-Br/C-Br coupling. We also established step-economical routes to [14] and [16]CPP using nickel-mediated C-Br/C-Br coupling. The final aromatization steps toward CPPs were accomplished with NaHSO4. Thus, combined with our previous size-selective synthesis of [12] and [14]-[16]CPP, we completed our size-selective synthesis of [9]-[16]CPP. The successful size-selective syntheses of [n]CPPs speak well for the flexibility and reliability of our strategy using a cyclohexane ring.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据